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Hydrothermal synthesis and structural characterization of organically templated zincophosphites: [Zn(C4N3H13)][Zn4(HPO3)6]⋅(C4N3H15) and [Zn5(H2O)4(HPO3)6]⋅(C7NH10)2(H2O)

✍ Scribed by Dong Zhang; Huijuan Yue; Zhan Shi; Min Guo; Shouhua Feng

Book ID
113913040
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
618 KB
Volume
8
Category
Article
ISSN
1293-2558

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✍ Alejandra V. Chavez; Tina M. Nenoff; Lakshitha Hannooman; William T.A. Harrison 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 241 KB

The solution-mediated syntheses and single crystal structures of (N 2 C 6 H 14 ) ' Zn(HPO 4 ) 2 ' H 2 O (I), H 3 N(CH 2 ) 3 NH 3 ' Zn 2 (HPO 4 ) 3 (II), and (N 2 C 6 H 14 ) ' Zn 3 (HPO 4 ) 4 (III) are described. These phases contain vertex-sharing ZnO 4 and HPO 4 tetrahedra, accompanied by doubly pr