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Hydrothermal synthesis and crystal structures of two novel rare earth coordination polymers based on pyridine-2,6-dicarboxylic acid

✍ Scribed by Liying Duan; Yangguang Li; Fuchen Liu; Enbo Wang; Xinlong Wang; Changwen Hu; Lin Xu


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
303 KB
Volume
689
Category
Article
ISSN
0022-2860

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✦ Synopsis


Two novel rare earth coordination polymers, [La(pydc)

were hydrothermally synthesized and characterized by the elemental analyses, IR spectra and TG analyses. Single crystal X-ray diffractions show that 1 and 2 are isostructural compounds. In the compounds of 1 and 2, the 1D lanthanide helical chains are connected each other by lanthanide binuclear dimer as building blocks to form a novel 3D covalent framework.


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