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Hydrothermal synthesis and crystal structure of novel bis(6-carboxypyridine-2-carboxylato-κ 3O 2 , N , O 6 )nickel(II) trihydrate, Ni(Hpydc) 2 ·3H 2 O

✍ Scribed by Sanotra, Sumit; Gupta, Rimpy; Sheikh, Haq Nawaz; Kalsotra, Bansi Lal; Gupta, Vivek K.; Rajnikant,


Book ID
119771218
Publisher
International Union of Crystallography
Year
2012
Tongue
English
Weight
670 KB
Volume
68
Category
Article
ISSN
0108-7681

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The title compound, [Ni(C 13 H 7 Br 2 N 2 O) 2 ], an Ni II complex of the Schiff base 2-(3,5-dibromo-2-hydroxyphenyl)benzimidazole, was synthesized by the reaction of 3,5-dibromosalicylaldehyde and 1,2-phenylenediamine. The molecule resides on a twofold rotation axis. The Ni II atom exists in a dist