A vanadium (V) monophosphate, KV 2 O 4 PO 4 , with an original tunnel structure has been synthesized. It crystallizes in the space group Pn2 1 a, with a ؍ 13.924(1) A s s , b ؍ 19.946(1) A s s , c ؍ 4.749(1) A s s . The [V 2 PO 8 ] framework consists of 903 3 oriented [V 2 O 8 ] pyramidal chai
Hydrothermal synthesis and crystal structure of a lead vanadium monophosphate hydrate with an open structure: Pb2V2O4(PO4)2·2H2O
✍ Scribed by Leclaire, Andre; Chardon, Josiane; Raveau, Bernard
- Book ID
- 125848022
- Publisher
- Royal Society of Chemistry
- Year
- 2001
- Tongue
- English
- Weight
- 193 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0959-9428
- DOI
- 10.1039/B009367J
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Two new \(\mathrm{Fe}^{\mathrm{Ill}}\) and \(\mathrm{V}^{\mathrm{ll}}\) phosphates, \(\mathrm{Ba}_{2} \mathrm{Fe}_{3} \mathrm{H}\left(\mathrm{PO}_{4}\right)_{2}\left(\mathrm{P}_{2} \mathrm{O}_{7}\right)_{2}\) and \(\mathrm{Ba}_{2} \mathrm{~V}_{3} \mathrm{H}_{2}\left(\mathrm{PO}_{4}\right)_{2}\left(\
The 5rst examples of vanadium gallophosphates, Rb[(VO)(H2O)Ga(PO4)2] and Cs[(VO)(H2O)Ga(PO4)2] have been synthesized using hydrothermal methods, from XVO3 (X ؍ Rb, Cs), Ga2O3, H3PO4, H2PO3F, and an organic species. The phases are isostructural and have a three-dimensional anionic vanadium gallopho