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Hydrothermal scandium fluoride chemistry: syntheses and crystal structures of [C2N2H10][ScF5], [NH4]2[Sc3F11] and [H3O][C6N2H16][ScF6]⋅H2O

✍ Scribed by Nicholas F. Stephens; Philip Lightfoot


Book ID
113913022
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
671 KB
Volume
8
Category
Article
ISSN
1293-2558

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Organically Templated Zirconium Fluoride
✍ Richard E. Sykora; Michael Ruf; Thomas E. Albrecht-Schmitt 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 403 KB

The organically templated Zr(IV) 6uorides, (C 2 H 10 N 2 ) Zr 2 F 10 ' H 2 O (AU2-6) and (C 4 H 12 N 2 )ZrF 6 ' H 2 O (AU1-6) have been prepared from the reaction of ZrO 2 with HF and ethylenediamine or piperazine under mild hydrothermal conditions. These compounds were characterized by single-cryst