Hydrothermal Preparation, Structures, and NLO Properties of the Rare Earth Molybdenyl Iodates Ln(MoO2)(IO3)4(OH) [Ln: Nd, Sm, Eu].
✍ Scribed by Thomas C. Shehee; Richard E. Sykora; Kang M. Ok; P. Shiv Halasyamani; Thomas E. Albrecht-Schmitt
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 93 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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The novel title compounds are prepared in about 90% yield by hydrothermal reaction of Ln2O3 with stoichiometric amounts of H3BO3 (H2O, 220 °C, autoclave, 3 d). The structures are investigated by powder XRD and single crystal XRD for Nd2B6O10(OH)4•H2O. The isostructural compounds crystallize in the m
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