Hydrostannolysis reactions. Part I. Reduction of esters.
β Scribed by L.E. Khoo; H.H. Lee
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 193 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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The retention behaviour of a number of series of l~on~ologous esters on a nonpolar stationary phase is reported together with correlations that are possible due to the structure of the compounds. The influence of the boiling point on retention is shown and the anomalous behaviour of methyl and isopr
Catalytic and chemical reductions of chiral pyrrolidine 13-enamino esters provides corresponding [3-amino esters with good to moderate diastereomer excesses. The unexpected major diastereomer 5 comes from a reduction process which amounts to an anti hydrogen addition.