Hydrostannation of C-C Multiple Bonds with Bu 3 SnH Prepared in situ from Bu 3 SnCl and Et 3 SiH in the Presence of Lewis Acid Catalysts. -A convenient method for the Lewis acid catalyzed hydrostannation of carbon-carbon multiple bonds is developed. The first hydrostannation of an alkene, cf. (VII),
✦ LIBER ✦
Hydrostannation of C–C multiple bonds with Bu3SnH prepared in situ from Bu3SnCl and Et3SiH in the presence of Lewis acid catalysts
✍ Scribed by Gevorgyan, Vladimir; Liu, Jian-Xiu; Yamamoto, Yoshinori
- Book ID
- 121245776
- Publisher
- Royal Society of Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 36 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1359-7345
- DOI
- 10.1039/A706187K
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## Abstract The scope of the B(C~6~F~5~)~3~‐catalyzed hydrosilylation of (X)Ph–CH=O and (X)Ph–C(R)=O was expanded to include a large set of substitutents (X = H, __p__‐Me, __o__‐Me, __p__‐F, __o__‐F, __p__‐Cl, __p__‐Br, __p__‐NO~2~, __m__‐NO~2~, __p__‐Et; R = Me or CF~3~). Reactions proceed at room