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Hydrosilylation of tetrasubstituted olefins

✍ Scribed by Konrad Oertle; Hansjürg Wetter

Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 196 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80873-x

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✦ Synopsis

Tetrasubstituted olefins are hydrosilylated under very mild conditions with dimethyl-or butylmethylchlorosilane and aluminium chloride as catalyst. Application of this procedure to 2,3-dimethyl-2-butene yields thexyldimethylsilyl chloride, a new silicon based protective group reagent.

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