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Hydrosilylation of Aldehydes and Ketones Catalyzed by Nickel PCP-Pincer Hydride Complexes

✍ Scribed by Chakraborty, Sumit; Krause, Jeanette A.; Guan, Hairong

Book ID
120358216
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
134 KB
Volume
28
Category
Article
ISSN
0276-7333

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Alkene Hydrogenation Catalyzed by Nickel
Alkene Hydrogenation Catalyzed by Nickel Hydride Complexes of an Aliphatic PNP Pincer Ligand
✍ Kalyan V. Vasudevan; Brian L. Scott; Susan K. Hanson πŸ“‚ Article πŸ“… 2012 πŸ› John Wiley and Sons 🌐 English βš– 525 KB

## Abstract To investigate metal–ligand cooperativity as a strategy for promoting nickel‐catalyzed alkene hydrogenation, cationic and neutral nickel(II) hydride complexes of the aliphatic pincer ligand PNHP^Cy^ {PNHP^Cy^ = HN[CH~2~CH~2~P(Cy)~2~]~2~} have been synthesized and characterized. Cationic