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Hydrosilylation of 1,3-dienes by phenylsilane

✍ Scribed by V. P. Yur'ev; I. M. Salimgareeva; O. Zh. Zhebarov; G. A. Tolstikov

Book ID
112480611
Publisher
Springer
Year
1975
Tongue
English
Weight
156 KB
Volume
24
Category
Article
ISSN
1573-9171

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πŸ“œ SIMILAR VOLUMES

RhCl(PPh3)3 catalyzed hydrosilylation of
RhCl(PPh3)3 catalyzed hydrosilylation of styrene and phenylacetylene with phenylsilanes
✍ Jubaraj B. Baruah; Kohtaro Osakada; Takakazu Yamamoto πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 733 KB

Reaction of styrene with Ph$iH? catalyzed by RhCl(PPh,)3 ( CO.3 mol%) proceeds smoothly in THF to give Ph,SiH( CH,CH,Ph) in 77-89% yields although the reaction is accompanied by formation of Ph,SiH( CH=CHPh), ethylbenzene, and Ph$iH in small amounts. Similar reaction in toluene also gives a mixture