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Hydrophosphination of Propargylic Alcohols and Amines with Phosphine Boranes

✍ Scribed by Busacca, Carl A.; Qu, Bo; Farber, Elisa; Haddad, Nizar; Grět, Nicole; Saha, Anjan K.; Eriksson, Magnus C.; Wu, Jiang-Ping; Fandrick, Keith R.; Han, Steve; Grinberg, Nelu; Ma, Shengli; Lee, Heewon; Li, Zhibin; Spinelli, Michael; Gold, Austin; Wang, Guijun; Wipf, Peter; Senanayake, Chris H.


Book ID
119966915
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
361 KB
Volume
15
Category
Article
ISSN
1523-7060

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Hydrophosphination of α,β-unsaturated es
✍ Karine Bourumeau; Annie-Claude Gaumont; Jean-Marc Denis 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 216 KB

The reactivity of primary phosphine-boranes RPH2'BH 3 (R = Ph and Me) towards CH2=CHCO2Me and CH2=CHP(O)(OMe)2 is discussed. Hydrophosphination is the major process. The presence of the free phosphine (0-20%) in the crude media indicates that a competitive hydroboration reaction also occurs. The P-H