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Hydrophobic Polymer-Supported Catalyst for Organic Reactions in Water: Acid-Catalyzed Hydrolysis of Thioesters and Transprotection of Thiols

✍ Scribed by Iimura, Shinya; Manabe, Kei; Kobayashi, Shū


Book ID
118201871
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
69 KB
Volume
5
Category
Article
ISSN
1523-7060

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## Abstract Several polystyrene‐supported proline dipeptides and a prolinamide derivative were prepared by thiol–ene coupling. These materials were used as catalysts for the direct asymmetric aldol reaction in water, and results compared with unsupported catalysts in water. Such an approach gave mo