Hydrophobic acceleration of Diels-Alder reactions
β Scribed by Rideout, Darryl C.; Breslow, Ronald
- Book ID
- 111671696
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 274 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The presence of biphenylenediol8 accelerates the rate of some Die&Alder reactions. Catalysis via a complex involving two hydrogen bona5 (see 6) is proposed. The development of catalysts for the asymmetric induction of Diels-Alder reactions is a subject of considerable current interest. To date, att
The widespread application of the retro-Diels-Alder reaction in synthesis has been hampered by the high temperatures usually required to cffect cycloreversion. The discovery of the anionic oxy-Cope reaction was followed by predictions that the accclerating effect of the oxide anion should also be ob