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Hydroperoxides as pseudohalides: oxidation, oxidative alkylation, acylation and arylation of acrylonitrile

โœ Scribed by Araneo, Silvia; Fontana, Francesca; Minisci, Francesco; Recupero, Francesco; Serri, Anna

Book ID
120085882
Publisher
The Royal Society of Chemistry
Year
1995
Tongue
English
Weight
237 KB
Volume
14
Category
Article
ISSN
0022-4936

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Effective asymmetric oxidation of enones
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Asymmetric epoxidation of aliphatic enones can be achieved with good conversions and high levels of enantiomeric excess using a catalyst, formulated as 6, derived from dibutylmagnesium and a range of dialkyl tartrates, with tert-butylhydroperoxide as the oxidant. This process works best with the add