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Hydroperoxide oxidations catalyzed by metals. IV. Molybdenum hexacarbonyl catalyzed epoxidation of 1-octene

✍ Scribed by Baker, T. N.; Mains, G. J.; Sheng, M. N.; Zajacek, J. G.


Book ID
126193316
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
473 KB
Volume
38
Category
Article
ISSN
0022-3263

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The Titanium(IV)-Catalyzed Epoxidation o
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A high catalytic activity towards alkene epoxidation is shown by titanium‐modified MCM41 mesoporous silicas if 2‐methyl‐1‐phenyl‐2‐propyl hydroperoxide (MPPH) is used as oxidant. This first example in which MPPH has been used as an efficient two‐electron oxidizing agent demonstrates that it is a com