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Hydrolytic cleavage of quaternized methylenebis (diphenylphosphine)

✍ Scribed by A.M. Aguiar; H.J. Aguiar; T.G. Archibald


Book ID
104250365
Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
211 KB
Volume
7
Category
Article
ISSN
0040-4039

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✦ Synopsis


We wish to report the faclle,.quantltatlve hydrolytic carbon to phosphorus bond cleavage of methylenebis(N-phenyldiphenylphosphine lmide)(I) under acidic conditions and methylenebis(benzyldiphenylphosphonium)dibromide (IV) under basic conditions (10% aqueous sodium hydroxide at 50" for


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Bis­[μ-methyl­enebis­(di­phenyl­phosphin
✍ Wei, Qiaohua ;Yin, Gangqiang ;Chen, Zhongning 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 228 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê R factor = 0.066 wR factor = 0.131 Data-to-parameter ratio = 14.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.