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Hydrolysis/Polycondensation in the Solid State: Access to Crystalline Silica-Based Hybrid Materials

✍ Scribed by Bruno Boury; Frédéric Ben; Robert J. P. Corriu

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 91 KB
Volume: 40
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3773(20010803)40:15<2853::aid-anie2853>3.0.co;2-j

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✦ Synopsis

Mild solid/gas or solid/liquid reactions can be used to prepare crystalline organosilicates, a class of silica-based hybrid materials, from the corresponding solid chlorosilanes. Hydrolysis and polycondensation in the solid state lead to the formation of the highly anisotropic organosilicates.

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