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Hydrolysis products of 4-acetamido-4-hydroxy-2-butenoic acid .gamma.-lactone

โœ Scribed by Grove, Michael D.; Weisleder, David

Book ID
127284824
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
332 KB
Volume
38
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

AM1 study of acid-catalyzed hydrolysis o
AM1 study of acid-catalyzed hydrolysis of maleamic (4-amino-4-oxo-2-butenoic) acids
โœ Toshiyuki Katagi ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 546 KB

The acid-catalyzed hydrolysis mechanisms of maleamic (4-amino-4-0~0-2-butenoic) acids were studied using AM1 method. The reaction proceeded mainly in two steps: (1) nucleophilic attack of the undissociated carboxyl group on the adjacent aminocarbonyl carbon via a zwitterionic intermediate; and ( 2 )