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Hydrolysis of the methyl 2-methylcyclohexanecarboxylates; conformational analysis of some cyclohexanecarboxylic derivatives

✍ Scribed by Lars H. Hellberg; Robert Peiffer; Thomas L. Jacobs; Russell Reed

Book ID
104215442
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
313 KB
Volume
9
Category
Article
ISSN
0040-4039

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✦ Synopsis

It has been reported (2) that cis-2-methyl-1-acetylcyclohexane [a] exists largely (at least -89%) in the conformation Is (rather than 58% II+ 42% Ia, approximately, assuming additivity of A-values (2,3) and ignoring other considerations), and [b] it reacts faster (33:l) towards hydroxylamine than its isomer (IIIa, neglecting the diaxial conformation). Considerations

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