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Hydrolysis of secondary alkyl sulphonates. S N2 reactions with high carbocation character

โœ Scribed by Bentley, T. William; Bowen, Christine T.

Book ID
120827382
Publisher
Royal Society of Chemistry
Year
1978
Tongue
English
Weight
787 KB
Volume
6
Category
Article
ISSN
1472-779X

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The reactions of P(1MeNCH,CH2),N, 1, with Mel, Etl, EtBv, n-PrBv, n-Btil, i-PrBr, PhCH,CHBrCH,, Me-CHBr(CH,),Me, s-BuBr, and t-BuBr were studied. The reactions of the primary alkyl halides produced the corresponding phosphonium cationic compounds, whereas the secondary and tertiary halides underwent