Hydrolysis of N-methyl-N-nitroso-p-toluenesulphonamide in micellar media

✍ Scribed by L. García-Río; P. Hervés; J. R. Leis; J. C. Mejuto; J. Perez-Juste

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 134 KB
• Volume: 11
• Category: Article
• ISSN: 0894-3230
• DOI: 10.1002/(sici)1099-1395(199808/09)11:8/9<584::aid-poc59>3.0.co;2-f

✦ Synopsis

The acid and basic hydrolysis of N-methyl-N-nitroso-p-toluenesulphonamide (MNTS) was studied in different micellar aggregates (CTACl, CTABr, TTABr, LTABr, and OTACl). The effect of mixed micelles (OTAX-LTAX) was also studied. The kinetic behaviour was explained on the basis of the pseudophase model, from which the binding constants of MNTS to different micelles, the ion exchange constants and the reactivity constants in the micellar pseudophase were obtained.