✦ LIBER ✦

Hydrolysis of Esters and Amides by the Metallo Nucleophile TpCum,MeZn–OH

✍ Scribed by Ruf, Michael ;Vahrenkamp, Heinrich

Book ID: 101816609
Publisher: Wiley (John Wiley & Sons)
Year: 1996
Tongue: English
Weight: 453 KB
Volume: 129
Category: Article
ISSN: 0009-2940
DOI: 10.1002/cber.19961290908

No coin nor oath required. For personal study only.

✦ Synopsis

Zinc hydroxide complexes I Pyrazolylborate ligand / Hydrolysis of esters and amides

The molecular zinc hydroxide complex TpC-rMeZn-OH 11, HOX or H2NX, resp. Two of them (TpCUm~MeZn-OCO-CH2-TpcumrMe = tris(3-cumenyl-5-methylpyrazolyl)hydroborate] is a CH20H resulting from propiolactone and TpCumrMeZnpowerful nucleophile. It effects stoichiometric hydrolysis of acti-OCO-CF, resulting from tnfluoroacetamide) were characterivated esters RCO-OX and amides RCO-NHX in nonaqueous zed by crystal structure determinations. media. The cleavage products are TpCumrMeZn-OCOR and

📜 SIMILAR VOLUMES

Hydrolysis of ester- and amide-type drug

Hydrolysis of ester- and amide-type drugs by the purified isoenzymes of nonspecific carboxylesterase from rat liver

✍ Rolf Mentlein; Eberhard Heymann 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 631 KB

Hydrolysis of Prostaglandin Glycerol Est

Hydrolysis of Prostaglandin Glycerol Esters by the Endocannabinoid-Hydrolyzing Enzymes, Monoacylglycerol Lipase and Fatty Acid Amide Hydrolase †

✍ Vila, Andrew; Rosengarth, Anja; Piomelli, Daniele; Cravatt, Benjamin; Marnett, L 📂 Article 📅 2007 🏛 American Chemical Society 🌐 English ⚖ 106 KB

Studies of the relationship between chem

Studies of the relationship between chemical structure and porphyria-inducing activity—V Hydrolysis of amides and esters by chick embryo liver amidases and esterases

✍ D.W. Schneck; G.S. Marks 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 703 KB

Cooperative Nucleophilic and General-Aci

Cooperative Nucleophilic and General-Acid Catalysis by the HisH + −His Pair and Arginine Transition State Binding in Catalysis of Ester Hydrolysis Reactions by Designed Helix−Loop−Helix Motifs

✍ Broo, Kerstin S.; Nilsson, Helena; Nilsson, Jonas; Flodberg, Anna; Baltzer, Lars 📂 Article 📅 1998 🏛 American Chemical Society 🌐 English ⚖ 78 KB