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Hydrolysis of CF3SF2Cl:NCF(CF3)2. Preparation of trifluoromethyl)(hexafluoroisopyropylideneamino)oxosulfur(VI)-containing compounds

โœ Scribed by Kitazume, Tomoya.; Shreeve, Jean'ne M.


Book ID
126017938
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
295 KB
Volume
16
Category
Article
ISSN
0020-1669

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Reactions of CF3SF3๎—ปNCF3 with nucleophil
โœ Shin-Liang Yu; Jean'ne M. Shreeve ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 464 KB

The new compounds, CF3SF(0)=NCF3 and CF3SF(=NCH3)=NCF3, result from nucleophilic displacement reactions of CF3SF3=NCF3 with water and methylamine, respectively. Higher yields of the di-imine are obtained when CH3N(Si(CH3)3)2 is substituted for CH3NH2. Stable fluoroamines, CF3SF4N(F)Rf (Rf = CF3, C2F