In the title compound, C~12~H~7~N~5~O~8~, the dihedral angle between the two benzene rings is 56.3β (2)Β°. The crystal packing is stabilized by intramolecular NβH...O and intermolecular CβH...O hydrogen bonds.
Hydrolysis of bis(2,4-dinitrophenyl) phosphate
β Scribed by Bunton, Clifford A.; Farber, S. J.
- Book ID
- 111654005
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 757 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Abstract The spontaneous hydrolysis of 2,4βdinitrophenyl phosphate dianion (2,4βDNPP) is speeded by cationic micelles of cetyltrimethylammonium salts [CTAX, X = Cl, Br, (SO~4~)~0.5~] and of bolaform(22)X~2~ [Me~3~N^+^ (CH~2~)__~n~__N^+^ Me~3~ 2X^β^, __n__ = 22, X = Br, (SO~4~)~0.5~]. The shorter
Wir danken der Deutscheu E'orschunysyemeinschaft, Bud Godes- berg, fiir die Unterstiitzung der corlieyenden Arheit.
The alkaline hydrolysis of the title ester was studied in 40% dioxane/water (v/v) solutions. Kinetic data, reactivity comparisons with model substrates and activation parameters ap-