Hydrolysis-assisted formation of a mononuclear, five-coordinate dihydroxotriiodocobaltate(II) ion
β Scribed by Darby, W. L.; Vallarino, L. M.
- Book ID
- 125980487
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 480 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The 16-electron, five-coordinate fluoro complex [RuF(dppp) 2 ]PF 6 (1a; dppp propane-1,3-diylbis[diphenylphosphine] smoothly reacts with 1,3-diphenylallyl bromide ( 1,1'-(3-bromoprop-1-ene-1,3-diyl)bis[benzene]) in dry CDCl 3 to give 1,3-diphenylallyl fluoride and [RuBr(dppp) 2 ] in nearly quantitat
Refluxing of the red compound [Cu II L 1 Κ(H 2 O)] (1) in acetone forms two new species: green NΠ-ethylenebis(3-ethoxysalicylaldimine)]. Whereas both 1 and 2 are converted into 3 upon heating, 3 is converted back into 1 when exposed to air. The structures of all three compounds were determined cryst