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Hydrolysis and rearrangement reactions of riboflavin phosphates : An explicit kinetic study

✍ Scribed by Peter NIELSEN; Jakob HARKSEN; Adelbert BACHER


Book ID
115123275
Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
776 KB
Volume
152
Category
Article
ISSN
1432-1327

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The reactions of a ribonuclease model substrate, the compound uridine-3'-p-nitrophenyl phosphate, have been examined using heavy-atom isotope effects and stereochemical analysis. The cyclization of this compound is subject to catalysis by general base (by imidazole buffer), specific base (by carbona