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Hydrolysis and alcoholysis of orthothioesters

โœ Scribed by Ellison, Robert A.; Woessner, Warren D.; Williams, Craig C.

Book ID
127340954
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
393 KB
Volume
39
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Fluorodesulfurization of aliphatic ortho
Fluorodesulfurization of aliphatic orthothioesters
โœ Timothy B. Patrick; Christine M. Hudson ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 151 KB

In contrast with aromatic orthothio esters that undergo desulfurative fluorination to produce trifluoromethyl substituted aromatics, aliphatic orthothio esters react with BrF with replacement of only one or two methylthio groups by fluorine. An elimination step often follows the first sulfur replace