Hydrological versus biogeochemical controls on catchment nitrate export: a test of the flushing mechanism

✍ Scribed by Carlos J. Ocampo; Carolyn E. Oldham; Murugesu Sivapalan; Jeffrey V. Turner

• Publisher: John Wiley and Sons
• Year: 2006
• Tongue: English
• Weight: 690 KB
• Volume: 20
• Category: Article
• ISSN: 0885-6087
• DOI: 10.1002/hyp.6311

✦ Synopsis

Deciphering the connection between streamflows and nitrate (NO 3 ) discharge requires identification of the various water flow pathways within a catchment, and the different time-scales at which hydrological and biogeochemical processes occur. Despite the complexity of the processes involved, many catchments around the world present a characteristic flushing response of NO 3 export. Yet the controls on the flushing response, and how they vary across space and time, are still not clearly understood. In this paper, the 'flushing response' of NO 3 export from a rural catchment in Western Australia was investigated using isotopic (deuterium), chemical (chloride, NO 3 ), and hydrometric data across different antecedent conditions and time-scales. The catchment streamflow was at all time-scales dominated by a pre-event water source, and the NO 3 discharge was correlated with the magnitude of areas contributing to saturation overland flow. The NO 3 discharge also appeared related to the shallow groundwater dynamics. Thus, the antecedent moisture condition of the catchment at seasonal and interannual time-scales had a major impact on the NO 3 flushing response. In particular, the dynamics of the shallow ephemeral perched aquifer drove a shift from hydrological controls on NO 3 discharge during the 'early flushing' stage to an apparent biogeochemical control on NO 3 discharge during the 'steady decline' stage of the flushing response. This temporally variable control hypothesis provides a new and alternative description of the mechanisms behind the commonly seen flushing response.