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Hydrogenolysis of Alkanes on Alumina Supported Platinum Kinetic Study and Effect of the Hydrocarbon Structure

✍ Scribed by G. Leclercq; L. Leclercq; R. Maurel


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
637 KB
Volume
88
Category
Article
ISSN
0037-9646

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✦ Synopsis


The k i n e t i c s o f t h e h y d r o g e n o l y s i s of some l i g h t s a t u r a t e d hydrocarbons h a s been s t u d i e d and t h e r e s u l t s have been r a t i o n a l i z e d by u s i n g a r a t e exp r e s s i o n d e r i v e d from t h e k i n e t i c scheme o r i g i n a l l y proposed by C I M I N O , BOUDART and TAYLOR f o r e t h a n e h y d r o g e n o l y s i s . h 'nH2n+2 * * 'nH2n+2-2a + aH2


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Kinetic compensation effects observed du
✍ Andrew K. Galwey; David G. Bettany; Michael Mortimer 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB

## Abstract The kinetic compensation effect (KCE) is a well‐known behavior pattern wherein a set of related reactions show a linear relationship between the calculated Arrhenius parameters, log~10~ __A__ and __E__~a~. Although various theoretical explanations have been advanced, none has yet found