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Hydrogenolysis of alkanes and olefin polymerization on the silica-supported zirconium hydrides: A comparative DFT study

✍ Scribed by Dmitri V. Besedin; Leila Yu. Ustynyuk; Yuri A. Ustynyuk; Valerij V. Lunin


Publisher
Springer
Year
2005
Tongue
English
Weight
514 KB
Volume
32
Category
Article
ISSN
1022-5528

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## Abstract A new Salan zirconium complex is synthesized and tested as a precatalyst for the polymerization of ethylene and higher __Ξ±__‐olefins. Its catalytic behavior is compared to that of a previously reported and related Salen zirconium complex. Analysis of the produced polyolefins reveals tha