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Hydrogen/deuterium exchange in electrolytic reduction reactions of phenyl ketones

✍ Scribed by Diaz, A. F.; Cheng, Y. Y.; Ochoa, M.


Book ID
126795670
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
501 KB
Volume
99
Category
Article
ISSN
0002-7863

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An ELDOR study of hydrogenβ€”deuterium exc
✍ L.D. Kispert; K. Chang; T.C.S. Chen πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 362 KB

ESR and ELDOR studies of glycineill crystals irradiated at -196Β°C and warmed to 22Β°C show that the radicaIs CDzCOO-and NHSCDCOO-stable bctwecn -140Β°C and -40Β°C undergo irreversible deuterium-hydrogen exchange rcactions above -40Β°C to form the radicals CHDCOO-and CH$OO-by a step-wise decay of cD2COO-