Hydrogenation of sorbic acid in mono- and biphasic systems catalyzed by Rh(I)- phosphine complexes
✍ Scribed by Udvardy, Antal ;Kathó, Ágnes
- Book ID
- 106512896
- Publisher
- Springer
- Year
- 2008
- Tongue
- English
- Weight
- 111 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0133-1736
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📜 SIMILAR VOLUMES
The reaction of [Ir(m-Cl)(COD)] 2 with various fluorous derivatives of triphenylphosphane containing a para-, meta-, or ortho-(1H,1H-perfluoroalkoxy)-substituted fluorous phosphane P(C 6 H 4 -ORf) 3 (Rf CH 2 C 7 F 15 , CH 2 CH 2 CH 2 C 8 F 17 ) and CO (1 atm) gives the corresponding trans-[Ir(m-Cl)(
Chelate complexes of the type [ Rh( q2-0,Z) (PR,),] (Z = CCH,, CCF3, CtBu, S( 0) -p-C&I&H,; PR, = PiPr,, PPhiPr,, PPh,iPr) catalyze the hydrogenation of phenylacetylene in toluene solution at 60°C. Selectivities close to 100% are achieved for the hydrogenation of the alkyne to the alkene in the pre