✦ LIBER ✦

Hydrogenation of olefins over palladium(II) complexes supported on a modified macroporous polymer bead

✍ Scribed by Jo, Young-Do; Ahn, Jou-Hyeon; Ihm, Son-Ki

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 383 KB
Volume: 44
Category: Article
ISSN: 0959-8103
DOI: 10.1002/(sici)1097-0126(199709)44:1<49::aid-pi807>3.0.co;2-g

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✦ Synopsis

Gellular and macroporous polymer supports have been prepared. A modiÐed polymer support has also been prepared by coating the internal pore wall of macroporous poly(styrene-co-divinylbenzene) with lightly crosslinked polymer containing functional groups. The supports were phosphinated and was supported on them. The supports and catalysts were characterized PdCl 2 using scanning electron microscopy and Fourier transform infrared spectroscopy. The polymer-supported Pd catalysts were used in the hydrogenation of oleÐns. The e †ects of the support structure and solvent were also studied.