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Hydrogenation of natural rubber in the presence of OsHCL(CO)(O2)(PCY3)2: Kinetics and mechanism

✍ Scribed by N. Hinchiranan; P. Prasassarakich; G. L. Rempel

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
210 KB
Volume
100
Category
Article
ISSN
0021-8995

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## Abstract The quantitative hydrogenation of __cis__‐1,4‐poly(isoprene) (CPIP) provides an easy entry to the alternating copolymer of ethylene–propylene, which is difficult to prepare by conventional polymerization. The homogeneous hydrogenation of CPIP, in the presence of OsHCl(CO)(O~2~)(PCy~3~)~