Hydrogenation of cis-1,4-polyisoprene catalyzed by Ru(CHCH(Ph))Cl(CO)(PCy3)2
β Scribed by R. Tangthongkul; P. Prasassarakich; N. T. McManus; G. L. Rempel
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 200 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0021-8995
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## Abstract In the presence of chlorinated solvents, the catalytic complex [Ir(COD)py(PCy~3~)]PF~6~ (where COD is 1,5βcyclooctadiene and py is pyridine) was an active catalyst for the hydrogenation of synthetic __cis__β1,4βpolyisoprene and natural rubber. Detailed kinetic and mechanistic studies fo