Hydrogenation of carbon monoxide to light olefins on iron-alumina catalysts
β Scribed by J. Barrault; C. Forquy; V. Perrichon
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 490 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0304-5102
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Iron-manganese catalyst supported on silicalite 1 was prepared by impregnation. The catalyst preparation was followed by X-ray diffraction, temperature-programmed reduction and Mtissbauer spectroscopy. Hydrogenation of CO was studied in a high pressure reactor by varying CO:H, ratio, temperature, an
When neat diene I is treated with a 2:l molar ratio of Fe,(CO), or Fe(CO)S at 85O in a glass pressure bottle for 12 hours, coupling occurs through the b 2.3 double bond yielding ketone II. The product is stereochemically pure by TLC on silica gel, and nmr. (m/e)+ = 344 7Okmp = 271-272.5" While the a