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Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium Trimethylphosphine Complexes: The Accelerating Effect of Certain Alcohols and Amines

✍ Scribed by Munshi, Pradip; Main, A. Denise; Linehan, John C.; Tai, Chih-Cheng; Jessop, Philip G.


Book ID
119950832
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
97 KB
Volume
124
Category
Article
ISSN
0002-7863

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Terminal alkynes with secondary amines idimethylamine, diethylamine, piperidine, morpholine) and CO 2 in the presence of mononuclear ruthenium catalysts, afford the vinyl carbamates RICH=CH-O-CONR2. The reaction studies suggest, as the active catalytic species, a ruthenium-vinylidene intermediate.