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Hydrogenation of .alpha.-methylstyrene by hydridopentacarbonylmanganese (I). Evidence for a free-radical mechanism

โœ Scribed by Sweany, Ray L.; Halpern, Jack


Book ID
126183983
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
390 KB
Volume
99
Category
Article
ISSN
0002-7863

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## Abstract The uncatalyzed transfer hydrogenation of substituted ฮฑโ€methylstyrenes with 9,10โ€dihydroanthracene (DHA), xanthene (XAN), or 9,10โ€dihydroacridine (DHAC) was studied mechanistically. The three hydrogen donors react at very similar rates and with similar activation parameters and with lit