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Hydrogenation of 2-pentyne over Pd/Al2O3 catalysts: Effect of operating variables and solvent selection

✍ Scribed by J.A. Bennett; R.P. Fishwick; R. Spence; J. Wood; J.M. Winterbottom; S.D. Jackson; E.H. Stitt


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
345 KB
Volume
364
Category
Article
ISSN
0926-860X

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Solvent effects in the hydrodechlorinati
✍ Santiago Gómez-Quero; Fernando Cárdenas-Lizana; Mark A. Keane 📂 Article 📅 2009 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 573 KB

## Abstract Solvent effects in the liquid phase (0.1 MPa; 303 K) hydrodechlorination (HDC) of 2,4‐dichlorophenol have been established over Pd/Al~2~O~3~. In the absence of secondary reactions, catalyst deactivation, and transport limitations, a stepwise HDC yields 2‐chlorophenol and phenol, where p