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Hydrogenation of 2-Butyne-1,4-diol Using Novel Bio-Palladium Catalysts

โœ Scribed by Wood, Joseph; Bodenes, Lucille; Bennett, James; Deplanche, Kevin; Macaskie, Lynne E.


Book ID
120380294
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
480 KB
Volume
49
Category
Article
ISSN
0888-5885

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Hydrogenation of 2-butyne-1,4-diol (B 3 D) using 1% Pt/CaCO 3 catalyst was carried out to give 2-butene-1,4-diol (B 2 D) or butane-1,4-diol (B 1 D) selectively or a mixture of two diols eliminating the formation of acetal, aldehyde, and alcohols as side products. In presence of ammonia, nearly compl