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Hydrogenation of 1,3-Diketones to Ketols

โœ Scribed by Stutsman, Paul S.; Adkins, Homer.


Book ID
120019010
Publisher
American Chemical Society
Year
1939
Tongue
English
Weight
468 KB
Volume
61
Category
Article
ISSN
0002-7863

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1,3-Diketones were reduced to 1,3-diols by using RuCl[N-(tosyl)-1,2-(diphenylethylenediamine) (h 6 -arene)] in the presence of formic acid and triethylamine. 1,3-Diols were obtained in good chemical yields and with high ee when symmetrical diketones were reduced.

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