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Hydrogenation Kinetics of 2,2-Dimethylol-1-butanal to Trimethylolpropane over a Supported Nickel Catalyst

✍ Scribed by Rantakylä, Tiina-Kaisa; Salmi, Tapio; Aumo, Jeannette; Mäki-Arvela, Päivi; Sjöholm, Rainer; Ollonqvist, Tapio; Väyrynen, Juhani; Lindfors, Lars Peter

Book ID
118208856
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
121 KB
Volume
39
Category
Article
ISSN
0888-5885

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Parallel hydrogenation of 2,2-dimethylol
Parallel hydrogenation of 2,2-dimethylol-1-butanal and formaldehyde over supported NiCr and CuCr catalysts
✍ Tiina-Kaisa Rantakylä; Tapio Salmi; Päivi Mäki-Arvela 📂 Article 📅 2002 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 172 KB

## Abstract The hydrogenation kinetics of 2,2‐dimethylol‐1‐butanal (TMP‐aldol) and formaldehyde were studied over two commercial supported catalysts; NiCr on silica and CuCr on alumina. Both catalysts hydrogenated the aldol selectively to triol, but the kinetic trends differed widely. With the nick