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Hydrogenation and Silylation of a Double-Cyclometalated Ruthenium Complex: Structures and Dynamic Behavior of Hydrido and Hydridosilicate Ruthenium Complexes

✍ Scribed by Scherl, Peter; Wadepohl, Hubert; Gade, Lutz H.


Book ID
126072313
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
592 KB
Volume
32
Category
Article
ISSN
0276-7333

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## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the