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Hydrogen transfer reactions in the formation of “Y + 2” sequence ions from protonated peptides

✍ Scribed by D. R. Mueller; M. Eckersley; W. J. Richter


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
337 KB
Volume
23
Category
Article
ISSN
1076-5174

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Protonation and Hydrogen Atom Abstractio
✍ Scott Charles; Janet A. Danis; Sundeep P. Mattamana; James C. Fettinger; Bryan W 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 122 KB

Ethylenediamine (en) solutions of [P 7 M(CO) 3 ] 3± (M = Cr, W) react with weak acids to give [HP 7 M(CO) 3 ] 2± ions where M = Cr (4 a) and W (4 b) in high yields. Competition studies with known acids revealed a pK a range for 4 b in DMSO of 17.9 to 22.6. The [P 7 M(CO) 3 ] 3± complexes also react