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Hydrogen-transfer polymerization of vinyl monomers derived from p-tolyl isocyanate and acrylamide derivatives

โœ Scribed by Takeru Iwamura; Ikuyoshi Tomita; Masato Suzuki; Takeshi Endo


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
144 KB
Volume
40
Category
Article
ISSN
1381-5148

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The anionic polymerization of N-acryloyl-Nะˆ-(4-methylbenzoyl)urea (1) was carried out at 80ยฐC for 24 h in DMF, DMSO, acetonitrile, or toluene by t-BuOK or DBU (3 mol %) as an initiator to obtain polymer 3 in a good yield. The structure of 3 was dependent upon the initiator used, in which t-BuOK sele

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The two new functional monomers, UMAI and UDMAI, having amide groups were prepared on reaction of methacryloyl isocyanate (MAI) with urea at low temperature. The monomers thus obtained were characterized by elemental analysis, as well as infrared, ultraviolet, 1 H and 13 C-NMR (nuclear magnetic reso