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Hydrogen spillover in catalytic reactions: I. Activation of alumina

✍ Scribed by Stanislav Jean Techner; Alain René Mazabrard; Gérard Pajonk; Gérard E.E Gardes; Can Hoang-Van

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
942 KB
Volume
58
Category
Article
ISSN
0021-9797

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Kinetic studies of the hydrogen peroxide decomposition catalyzed by the dimeric Mn(I1)-gluconate complex, in alkaline medium, showed evidence for the oxidative cleavage of the ligand, leading to the formation of formaldehyde as one of Lie products. In the presence of a large excess of other hydroxyl