Hydrogen pressure equivalent to overpotential on Pd + Ag alloy electrodes in acidic solutions in the presence of thiourea

The hydrogen pressure equivalent to the

The hydrogen pressure equivalent to the overpotential: observation on Pd hydrogen electrode and interpretation on the basis of a mixed-controlled mechanism

✍ M. Enyo 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 716 KB

A quantitative analysis is presented of the hydrogen pressure that is in equilibrium with adsorbed hydrogen at a Pd cathode and discussed on the basis of a mixed-controlled Volmer-Tafel mechanism of the hydrogen electrode reaction. Experimental evidence which supports this, but not the Volmer-Heyrov