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Hydrogen Peroxide Producers Look to New Markets for Growth

✍ Scribed by AINSWORTH, SUSAN J.


Book ID
126583150
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
278 KB
Volume
67
Category
Article
ISSN
0009-2347

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New ligands for manganese catalysed sele
✍ Jelle Brinksma; RenΓ© La Crois; Ben L Feringa; Maria Irene Donnoli; Carlo Rosini πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 74 KB

In situ prepared manganese complexes with ligands 1-5 have been used in the catalytic oxidation of sulfides to sulfoxides using hydrogen peroxide at 0Β°C in acetone. Using ligand 4, methyl phenyl sulfoxide is obtained in 55% yield and turnover numbers up to 250, while the formation of sulfone is almo