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Hydrogen peroxide oxidation of alkyl aromatic hydrocarbons catalyzed by Keggin-type polyoxometalates

✍ Scribed by Donato Attanasio; Daniela Orru'; Lorenza Suber

Publisher
Elsevier Science
Year
1989
Weight
283 KB
Volume
57
Category
Article
ISSN
0304-5102

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The hydroxylation of a series of aromatic hydrocarbons with hydrogen peroxide, catalyzed by iron complexes with pyrazine-3-carboxylic acid N-oxide, was investigated, operating in a biphasic reaction medium. The new catalyst showed a high selectivity to the corresponding phenols, minimizing the over